Calculating the energy barrier that keeps liquid water below zero from immediately turning into ice provides the key to understanding its ability to be compressed as temperature drops. Water behaves in mysterious ways. Especially below zero, where it is dubbed supercooled water, before it turns into ice. Physicists have recently observed the spontaneous first steps of the ice formation process, as tiny crystal clusters as small as 15 molecules start to exhibit the recognizable structural pattern of crystalline ice.
http://feeds.sciencedaily.com/~r/sciencedaily/~3/FIi4IxQjJLo/150521082406.htm
How supercooled water is prevented from turning into ice
21 May 2015
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